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Silicon
Silicon is, by far, the most common semiconductor material used in solar cells, representing approximately 95% of the modules sold today. It is also the second most abundant material on Earth (after oxygen) and the most common semiconductor used in computer chips. Crystalline silicon cells are made of silicon atoms connected to one another to form a crystal lattice. This lattice provides an organized structure that makes conversion of light into electricity more efficient.
Solar cells made out of silicon currently provide a combination of high efficiency, low cost, and long lifetime. Modules are expected to last for 25 years or more, still producing more than 80% of their original power after this time.
Thin-Film Photovoltaics
A thin-film solar cell is made by depositing one or more thin layers of PV material on a supporting material such as glass, plastic, or metal. There are two main types of thin-film PV semiconductors on the market today: cadmium telluride (CdTe) and copper indium gallium diselenide (CIGS). Both materials can be deposited directly onto either the front or back of the module surface.
CdTe is the second-most common PV material after silicon, and CdTe cells can be made using low-cost manufacturing processes. While this makes them a cost-effective alternative, their efficiencies still aren’t quite as high as silicon. CIGS cells have optimal properties for a PV material and high efficiencies in the lab, but the complexity involved in combining four elements makes the transition from lab to manufacturing more challenging. Both CdTe and CIGS require more protection than silicon to enable long-lasting operation outdoors.
Perovskite Photovoltaics
Perovskite solar cells are a type of thin-film cell and are named after their characteristic crystal structure. Perovskite cells are built with layers of materials that are printed, coated, or vacuum-deposited onto an underlying support layer, known as the substrate. They are typically easy to assemble and can reach efficiencies similar to crystalline silicon. In the lab, perovskite solar cell efficiencies have improved faster than any other PV material, from 3% in 2009 to over 25% in 2020. To be commercially viable, perovskite PV cells have to become stable enough to survive 20 years outdoors, so researchers are working on making them more durable and developing large-scale, low-cost manufacturing techniques.
Organic Photovoltaics
Organic PV, or OPV, cells are composed of carbon-rich (organic) compounds and can be tailored to enhance a specific function of the PV cell, such as bandgap, transparency, or color. OPV cells are currently only about half as efficient as crystalline silicon cells and have shorter operating lifetimes, but could be less expensive to manufacture in high volumes. They can also be applied to a variety of supporting materials, such as flexible plastic, making OPV able to serve a wide variety of uses.PV
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